The biosynthetic pathway of 1 was disclosed first by Bode and Zeeck, 4, 8 and further by Müller and co-workers 9 (Scheme 1). It was proposed that the ansa-chain is added onto the benzoic acid 2 or its ...
The polysaccharide β-1,2-glucan consists of repeating units of glucose linked together by β-1,2-glycosidic bonds. Cyclic β-1,2-glucans (CβGs) occur in different bacterial species and have a role in ...
The Diels-Alder reaction, a widely used transformation in organic synthesis, forms six-membered rings from a conjugated diene and a dienophile-frequently an alkene. Usually, these two reactants must ...
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